Brazil head Down Under for games against Argentina (June 9) and Australia (June 13) to be played at the MCG.
SEE THE FULL SQUAD LISTS BELOW
Barcelona star Neymar was the big name omission from coach Tite’s squad, while Real Madrid duo Marcelo and Casemiro also aren’t included due to their involvement in the UEFA Champions League (UCL) Final.
"The emotional side of the game drains us...the adrenaline is at a million every single day, the players need mental rest," Tite told a news conference after announcing his squad.
"There is a team-building and there is consolidation, but this is about construction at the moment."
Neymar’s absence means he won’t get the chance to go up against his Barcelona team-mate Lionel Messi, who has been included in Argentina’s star-studded squad.
Juventus’ in-form attackers Paulo Dybala and Gonzalo Higuain have also been included in the Argentina squad, despite their involvement in the UCL final in Cardiff just five days earlier.
The Caltex Socceroos take on Brazil just five days after their crucial FIFA World Cup qualifier against Saudi Arabia in Adelaide on June 8.
The match against the South American powerhouses will provide vital preparation for the FIFA Confederations Cup tournament, with Australia to take on Germany, Chile and Cameroon in Group B.
The Caltex Socceroos tackle Saudi Arabia in a crucial World Cup Qualifer in Adelaide on June 8. Click Here for Tickets
Goalkeepers: Diego Alves (Valencia), Weverton (Atletico Paranaense), Ederson (Benfica)
Defenders: Alex Sandro (Juventus), David Luiz (Chelsea), Fagner (Corinthians), Filipe Luis (Atletico Madrid), Gil (Shandong Luneng), Jemerson (Monaco), Rafinha (Bayern Munich), Rodrigo Caio (Sao Paulo), Thiago Silva (Paris Saint-Germain)
Midfielders: Fernandinho (Manchester City), Giuliano (Zenit), Lucas Lima (Santos), Paulinho (Guangzhou Evergrande), Philippe Coutinho (Liverpool), Renato Augusto (Beijing Gouan), Rodriguinho (Corinthians), Willian (Chelsea)
Forwards: Diego Souza (Sport), Douglas Costa (Bayern Munich), Gabriel Jesus (Manchester City), Taison (Shakhtar Donetsk)
Goalkeepers: Nahuel Guzman (Tigres), Sergio Romero (Manchester United), Geronimo Rulli (Real Sociedad)
Defenders: Emanuel Mammana (Lyon), Gabriel Mercado (Sevilla), Javier Mascherano (Barcelona), Nicolas Otamendi (Manchester City).
Midfielders: Ever Banega (Inter), Lucas Biglia (Lazio), Manuel Lanzini (West Ham United), Leandro Paredes (Roma), Guido Rodriguez (Tijuana), Eduardo Salvio (Benfica)
Forwards: Joaquin Correa (Sevilla), Angel Di Maria (PSG), Paulo Dybala (Juventus), Alejandro Gomez (Atalanta), Gonzalo Higuain (Juventus), Mauco Icardi (Inter), Lionel Messi (Barcelona)